Rihanna's vocals were recorded by Marcus Tovar and Kuk Harrell at Westlake Recording Studios in Los Angeles, California, while it was mixed by Manny Marroquin at Larrabee Studios in Burbank, California.
The song features vocals by American singer-rapper Future who also co-wrote, and music produced by George Jackson (previously known as Luney Tunez), Emmanuel Zaragoza (previously known as Mex Manny) and Future.
Additional writing was done by Denisia "Blu June" Andrews and Rihanna herself.
"Loveeeeeee Song" is a sci-fi slow R&B song, that features lyrics the revolve around themes of love and affection that hear Rihanna singing in an accent.
In an interview with Complex he stated, "that was one of the beats I really don't like. When I made it, I was in the mindset of being real, melodic, laid back, and sexy." He further added that from the beginning he was aware that the song will be a "pop-female record" and that he also didn't want to put too many instruments in it.
Luney Tunez labeled it as one of the favorite songs that he has ever produced.
In an interview for MTV News, Future spoke about his collaboration with Rihanna, "They wanted a more uptempo record, so I sent four or five records, and I left the last record.
It was more like a ballad, and I left it." He further revealed that the original title of the song was "Love & Affection", however, Rihanna's mentor Jay-Z changed it to "Love Song" and added two additional 'e's becoming "Loveee Song".
"Loveeeeeee Song" received general acclaim, some of whom complimented Rihanna's vocals and called it a "stand-out track, while others called the song a "touching duet".
It has since then peaked at number 55 on the US Billboard Hot 100 and charted on the R&B Chart at number 17 in the United Kingdom.
On September 12, 2012, Def Jam France announced via Twitter that Rihanna would release a new single the upcoming week while her seventh studio album is scheduled to be released in November 2012.
However, the tweet was shortly deleted and replaced with another clarifying that "more information will be made available tomorrow, Thursday, September 13".